Hi Novafix,
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The Presence setting is just for the ‘User’ type field. It cannot work in the normal field.
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But I may have a workaround for you by configuring the custom field, you can try to change the Calculated Value as below:
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<span><img src="/_layouts/images/imnhdr.gif" onload="IMNRC('<%EMail%>')" id="<%ID%>" name="imnmark<%ID%>" ShowofflinePawn = "1" border="0" height="12" valign="middle" /><a href="mailto:<%EMail%>"><%Name%></a></span>
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The <%Email%> field is referring to the email address.
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